Relevant identified uses of the substance or mixture and uses advised against Intended use Application Method 1.3. When tags are used, the UN number must be displayed on the primary class label or on the tag next to the primary class label. 2. Used to display the UN number on a large means of containment (greater than 450 L) when the UN number is not included in the hazard class placard. Self-heating solid, toxic, organic, n.o.s. Methylmercury and other organic compounds. Access to this website Flash point: We do not provide consultancy services. For pure chemical substances or well-defined articles, it is easy to choose UN numbers and proper shipping names. Specific chemical name (e.g., acetone, sulfuric acid, etc. p;k0;!N}?s7S&7! Wastes: Transportation of Dangerous Goods (TDG) - Dangerous Goods Safety Marks (Road), All Can I use a UN number that is not included in the Canadian TDG Regulations? 4 0 obj hbbd``b`$@@YD$;! means Not Otherwise Specified. When test results and the hazard class criteria are compared, there are three possible conclusions: a) The laboratory test results show the product does not meet any of the criteria for the hazard classes. Although every effort is made to ensure the accuracy, currency and completeness of the information, CCOHS does not guarantee, warrant, represent or undertake that the information provided is correct, accurate or current. Safety Data Sheet Mercury (Metallic) - WMSolutions.com Depending on the classification of the dangerous good, one or more of the following safety marks may be required on a small means of containment: See Figure 2 for an example of dangerous goods safety marks on a small means of containment such as a package. Transportation of Dangerous Goods (TDG) - 9 Classes, TDG "Special Case and Special Provision Exemptions. EDT. The alphabetical order has been determined by ignoring all numerical digits and all lower case letters that precede the first capital letter in the shipping name. the date on which the dangerous goods were classified. But a sealed glass ampule holding mercurywhen the ampule is in the form of a long cylinder with lines marked on the side for measuring temperatureis a thermometer, a mercury article, and would be shipped as "UN 3506, MERCURY Note: This document is a general overview of the TDG classification requirements. Download the OSH Answers app for free. (i) The words Class or Division may be included preceding the primary and subsidiary hazard class or division numbers. If you are a consultant, you may get yourself listed in CSP business directory (free) or Guide for Preparing SHIPPING PAPERS - Transportation The Class 9, lithium battery label, must be displayed on a small means of containment for the following dangerous goods: When a shipment consists of batteries with different UN numbers, all applicable UN numbers must be indicated on one lithium battery or the UN number can be included on separate lithium marks. Indication of the packaging specification number (1H1) may be included in the description of the package (for example, 12 1H1 drums or 12 drums (UN 1A1)). Placard for the subsidiary hazard class (if any) next to the primary hazard class placard on each side and each end (total of four) for: Each dangerous good that must have an ERAP. (viii) For authorized consumer commodities, the information provided may be either the gross mass of each package or the average gross mass of the packages. It is determined according to the specification in section 2.8 and the Precedence of Classes Table which is provided in Part 2. See Special Provision 34 in Schedule 2 of the TDG Regulations. (6) For transportation by aircraft, the total net mass per package, must be shown unless a gross mass is indicated in Columns (9A) or (9B) of the 172.101 table in which case the total gross mass per package must be shown; or, for Class 7 materials, the quantity of radioactive material must be shown by activity. EDT. N.O.S. Figure 4: Placard requirements and placement for compartmentalized means of containment. Sodium dithionite or Sodium hydrosulphite, Sodium sulphide, anhydrous or Sodium sulphide, with less than 30% water of crystallization, Dangerous Goods of Class4.2, Packing Group II, not listed above, Fibres or Fabrics, animal or vegetable or synthetic, n.o.s., with oil, Iron oxide, spent or Iron sponge, spent, obtained from hydrocarbon gas purification, Seed cake, with more than 1.5% oil and not more than 11% moisture, Seed cake, with not more than 1.5% oil and not more than 11% moisture. Dangerous Goods Safety Marks - Transport Canada The Mercury WebClassification of dangerous goods is broken down into nine classes according to the type of danger materials or items present, click on a class to read more details; 1. Column 4 Subsidiary Risk(s) Contains the class number(s) of any subsidiary risk(s). X`I%&/m{JJt`$@iG#)*eVe]f@{{;N'?\fdlJ!?~|? Note that these types of products do not have a UN Number. :), How to Assign UN Packing Group for Dangerous Goods. Mercury's surface temperatures are If you are a consultant, you may get yourself listed in CSP business directory (free) or Are safety marks required on consolidation bins? Generic risk (e.g., flammable, toxic, etc.). (vii) for dangerous goods that are subject to special provision 23, the words toxic by inhalation or toxic inhalation hazard or toxique par inhalation or toxicit par inhalation; Examples of classification descriptions of dangerous goods are: UN1214, ISOBUTYLAMINE, Class 3, Subsidiary Class (8), II, UN1214, ISOBUTYLAMINE, Class 3(8), Packing Group II, UN3381, TOXIC BY INHALATION LIQUID, N.O.S., Class 6.1 PG I, UN 1075 LIQUEFIED PETROLEUM GASES (propane); Not odourized, Class 2.1. when all of the dangerous good safety marks can be seen through the overpack for each class of dangerous goods that is inside it, no additional labels or safety marks are required. Shipping Limited Quantities or Excepted Quantities from This requirement is outlined in Part 5 of the TDG Regulations. (7) The number and type of packages must be indicated. Select country for which that subsidiary belongs to. Marine Pollutants: Mercury and its compounds. Are there any exemptions for placards? Generally, the shipping name should be selected in the following hierarchical order: 1. This communication is accomplished by the: Note that the difference between labels and placards is their size. The symbol P used in this schedule means that the handling, offering for transport, and transporting of the dangerous goods by rail is prohibited. A label is used for a small means of containment whose capacity is 450 L or less. For the dangerous goods other than Class 1 DG, a Conveyance Permit (For Dangerous Goods other than Class 1 Dangerous Goods) is required. It would be shipped as "UN 2809, MERCURY, 8(6.1)" and assigned to Packing Group II. (iii) The following are excepted from the requirements of paragraph (a)(5) of this section: (A) Bulk packages, provided some indication of the total quantity is shown, for example, 1 cargo tank or 2 IBCs., (B) Cylinders, provided some indication of the total quantity is shown, for example, 10 cylinders.. Yes. Figure 3: Labels on cylinders. 172.202 Description of hazardous material on shipping papers. Wis. Admin. They will be used to label dangerous goods. Class 6.1 (5.1) Packing Group I. Abbreviations may be used to express units of measurement and types of packagings. (vii) For hazardous materials in limited quantities, the total net quantity per package must be shown unless a gross mass is indicated in Column 4 of 173.27 Table 3, in which case the total gross mass per package must be shown. This mark is required when shipments meet the limited quantity exemption, and must be displayed on one side of a means of containment. ), 2. Wastes: If the product is a waste, then the shipping name is either preceded or followed by the word waste. Access to this website Mercury is a highly toxic metal and can cause skin irritation, skin rashes, allergic reactions. Classification Containing Methanol Transportation of Dangerous Goods (TDG) - Classification Large means of containment: These words must be displayed on two opposite sides of the large means of containment in addition to any other safety marks that are required under the TDG Regulations. (iii) For domestic shipments, primary and subsidiary hazard class or division names may be entered following the numerical hazard class or division, or following the basic description. The rules are set out in a table, the segregation table in 7.2.4, and also have to be applied in respect of any subsidiary class. However, if the product's name is not listed in Schedule 1 or 3, then the product must be tested at a laboratory. (ii) The hazard class need not be included for the entry Combustible liquid, n.o.s.. Primary Class This column gives the primary class of the dangerous goods. A proof of classification is a document that the consignor must provide, upon request, to the federal Minister of Transport. hmk0`oW,PIl/J_hH ]lwY8>Kwg"e.RN B 4$&ECI* pZN6'4pI %;=KzU?_ojW{tO&1>I4ZeQ6gVO5"_|v"8[UD How do I assign Categories A and B for the infectious substances? Other safety marks are shown in Table 2 in this document (below). The type of packages must be indicated by description of the package (for example, 12 drums). Mercury also combines with carbon to make organic mercury compounds. Regs. WebMercury Marineis a marine enginedivision of Brunswick Corporationheadquartered in Fond du Lac, Wisconsin. How to Ship Hazmat with No Packing Group | Lion Technology NOTE: The table below is for guidance purposes only. :/z6+^OHfamwfe~:[NF/{^f&onaR;`N=EIM&&G* mG6[0b@,d a|};>Swhl_qmlc/ZI/*_:y,B.y'WvPkzZ. How do I determine the shipping name when there are several possible shipping names? 1289 0 obj <>/Filter/FlateDecode/ID[]/Index[1273 31]/Info 1272 0 R/Length 79/Prev 99077/Root 1274 0 R/Size 1304/Type/XRef/W[1 2 1]>>stream (v) the subsidiary class or classes, in parentheses, which may be shown as a number only or under the heading subsidiary class or classe subsidiaire or following the words subsidiary class or classe subsidiaire, except that, for transport by aircraft or by ship, the subsidiary class or classes may be shown after the information required by this paragraph, (vi) the packing group roman numeral, which may be shown under the heading PG or GE or following the letters PG or GE or following the words Packing Group or Groupe d'emballage, and. There are 9 dangerous goods classes. Some of the classes can be further divided into divisions, e.g., Class 1, while others do not have sub-divisions, e.g., Class 3. class 28-35-189a - 28-35-189a - Advance notification of transport of nuclear waste, Kan. Admin. The metal is obtained by heating cinnabar in a current of air and condensing the vapour. See Column 4 in Schedule 1. Code R9-7-1508 - R9-7-1508 - Advance Notification of Nuclear Waste Transportation. Information on how to do the assignment is provided in Section 2.36 of Part 2. Where can I get my product analyzed for classification? As Marine Pollutants Only: (1) The total quantity of the material covered by one description must appear before or after, or both before and after, the description required and authorized by this subpart. You may experience longer than usual wait times or partial service interruptions. (d) Technical and chemical group names may be entered in parentheses between the proper shipping name and hazard class or following the basic description. The classes in which the dangerous goods are included are ranked in order of precedence in accordance with Section 2.8 to determine the primary class and the potential subsidiary class or classes; The potential PG is See the example below. Although a consignor may also use the classification of the manufacturer or a previous consignor, the consignor is still responsible for making sure the classification is correct, and for making a proof of classification available to the Minister. Is "Waste", "Molten", "Stabilized", "Flash point", "Marine Pollutant" applicable. If you cannot get through, please contact us by email. Phosphorus sesquisulphide, free from yellow and white phosphorus, Rubber scrap or Rubber shoddy, powdered or granulated, not greater than 840 mm and rubber content greater than 45%. An appropriate modifier, such as contains or containing, and/or the percentage of the technical constituent may also be used. subsidiary class Consult Schedule 3 for the shipping name that most precisely describes the dangerous goods. If you like this article, please share it. I, II or III) assigned to the substance or article. It can cause headaches, can damage the nervous system of the body. Shipping name is the name of the dangerous good as it appears in column 2 of Schedule 1. These criteria are outlined in the TDG Regulations. 391-3-17-.06 - Rule 391-3-17-.06 - Transportation of Radioactive Material, 410 Ind. Figure 2: Safety marks on a small means of containment such as a package Note 1: The orientation marks for liquids are optional for road transport, but mandatory for air transport. Although every effort is made to ensure the accuracy, currency and completeness of the information, CCOHS does not guarantee, warrant, represent or undertake that the information provided is correct, accurate or current. How does the consignor determine the classification for a dangerous good? SAFETY DATA SHEET - Fisher Sci Note: when there are several options for a shipping name, the shipping name should be assigned in a hierarchical order (described further below). Oxidizing 6. View Past Newsletter, http://www.unece.org/fileadmin/DAM/trans/danger/publi/adr/adr2011/English/Part3.pdf, http://www.phmsa.dot.gov/filename/Marine_Pollutant_Guidance.pdf, Biocides and Biocidal Product Regulations, Example: UN 1133 ADHESIVES containing flammable liquids; UN 1263, PAINT, Example: UN 1987 ALCOHOLS, N.O.S. Not required to be displayed on road vehicles. NOTE: See further belowin the table for placard requirement when the hazard class is 1.1, 1.2, 1.3, 1.4 or 1.5 are above a certain threshold of gross mass/number of articles. Generally, if the shipment includes dangerous goods in Class 7, Radioactive Materials, then two labels are required on the small means of containment. Meanwhile the actual assigned category is obtained from Appendix 3 in Part 2. Class 2.1 Dangerous Goods If the product's name (e.g., chemical name) is listed in Schedule 1 or 3, the primary hazard class is listed in Column 3 of Schedule 1 as well as in Column 2 of Schedule 3 for that shipping name. See Section 1.17 in the TDG Regulations. For an explosive that is an article, such as Cartridges, small arms, the net explosive mass may be expressed in terms of the net mass of either the article or the explosive materials contained in the article. }qI;<>q2=4s; y5J as appropriate. % Determine the shipping name: Check if the product name is listed in Schedule 1 or Schedule 3. You can download all hazard symbols for all hazard classes above by clicking the picture below. Scheduled maintenance - Thursday, July 12 at 5:00 PM More than one subsidiary class is possible. Column 5 Packing Group Contains the packing group number (i.e. Note 3: The containers inside the package not required to bear TDG safety marks. Has a subsidiary classification of Class 1 (1.1,1.2, 1.3 above the exemption limits), Class 4.3, Class 6.1 (Packing Group I), Class 8 (applies only to UN numbers N2977 and UN2978). Ch. WebClass 1 Explosives; Class 2 Gases; Class 3 Flammable liquids; Class 4 Other Flammable Substances; Class 5 Oxidizing Substances & Organic Peroxides; Class 6 In this article, we will share with you some rules you need to follow when choosing UN numbers and proper shipping names. UN-2 a document that explains how the dangerous goods were classified.